Early diagenesis of redox-sensitive trace metals in the northern Okinawa Trough

Wang Xiaojing Li Li Liu Jihua Wu Yonghua Gao Jingjing Cao Peng Zhang Ying Shi Xuefa

王小静, 李力, 刘季花, 吴永华, 高晶晶, 曹鹏, 张颖, 石学法. 冲绳海槽北部氧化还原敏感元素的早期成岩过程[J]. 海洋学报英文版, 2019, 38(12): 14-25. doi: 10.1007/s13131-019-1512-5
引用本文: 王小静, 李力, 刘季花, 吴永华, 高晶晶, 曹鹏, 张颖, 石学法. 冲绳海槽北部氧化还原敏感元素的早期成岩过程[J]. 海洋学报英文版, 2019, 38(12): 14-25. doi: 10.1007/s13131-019-1512-5
Wang Xiaojing, Li Li, Liu Jihua, Wu Yonghua, Gao Jingjing, Cao Peng, Zhang Ying, Shi Xuefa. Early diagenesis of redox-sensitive trace metals in the northern Okinawa Trough[J]. Acta Oceanologica Sinica, 2019, 38(12): 14-25. doi: 10.1007/s13131-019-1512-5
Citation: Wang Xiaojing, Li Li, Liu Jihua, Wu Yonghua, Gao Jingjing, Cao Peng, Zhang Ying, Shi Xuefa. Early diagenesis of redox-sensitive trace metals in the northern Okinawa Trough[J]. Acta Oceanologica Sinica, 2019, 38(12): 14-25. doi: 10.1007/s13131-019-1512-5

冲绳海槽北部氧化还原敏感元素的早期成岩过程

doi: 10.1007/s13131-019-1512-5
基金项目: The National Key Basic Research Program of China under contract No. 2013CB429704; the NSFC-Shandong Joint Fund for Marine Science Research Centers under contract No. U1606401; the National Natural Science Foundation of China under contract No. 41776095; the National Program on Global Change and Air-Sea Interaction under contract No. GASI-GEOGE-03.

Early diagenesis of redox-sensitive trace metals in the northern Okinawa Trough

  • 摘要: 本文利用冲绳海槽北部的5根沉积物短柱(~25 cm),对氧化还原敏感元素(Mo、U、V)在早期成岩过程中的地球化学行为进行了系统的研究,探讨了影响其分布的主控因素,并定量估算了其在沉积物-海水界面扩散通量和沉积物中的自生累积埋藏通量,为阐明西北太平洋边缘海地区氧化还原敏感元素的早期成岩过程提供了科学依据。结合孔隙水及沉积物中Fe、Mn、Mo、U和V的垂向分布结果发现,所有沉积物短柱的沉积环境介于氧化和次氧化之间,直到短柱底部均未达到缺氧环境。Mo的早期成岩受到Mn氧化物地球化学循环过程的影响,在沉积物中基本没有自生累积。U在沉积物短柱的含量随着深度的增加而增加,自生累积通量(MAR)约为长江和黄河输入量的23%左右。沉积物-海水扩散通量与沉积物自生累计通量对比发现,U为向下扩散进入沉积物,而V为向上扩散进入上覆水体,扩散通量的方向和大小与自生累积通量基本一致,说明扩散过程是控制U和V在沉积物中埋藏或者迁移的主要因素。
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