ZHAO Jianru, CHU Fengyou, JIN Xianglong, WU Qingsong, YANG Kehong, GE Qian, JIN Lu. The spatial multiscale variability of heavy metals based on factorial kriging analysis:A case study in the northeastern Beibu Gulf[J]. Acta Oceanologica Sinica, 2015, 34(12): 137-146. doi: 10.1007/s13131-015-0768-7
Citation: ZHAO Jianru, CHU Fengyou, JIN Xianglong, WU Qingsong, YANG Kehong, GE Qian, JIN Lu. The spatial multiscale variability of heavy metals based on factorial kriging analysis:A case study in the northeastern Beibu Gulf[J]. Acta Oceanologica Sinica, 2015, 34(12): 137-146. doi: 10.1007/s13131-015-0768-7

The spatial multiscale variability of heavy metals based on factorial kriging analysis:A case study in the northeastern Beibu Gulf

doi: 10.1007/s13131-015-0768-7
  • Received Date: 2014-08-15
  • Rev Recd Date: 2014-11-28
  • Factorial kriging analysis is applied to the research on the spatial multiscale variability of heavy metals in submarine. It is used to analyze the multiscale spatial structures of seven heavy metals, Ni, Cu, Zn, Pb, Cr, As and Cd in the surface sediment from the northeastern of Beibu Gulf, identify and separate spatial variations at different scales of heavy metals, and discuss the provenance of heavy metals and the influencing factors. The results show that the existence of three-scale spatial variations those consist of nugget effect, a spherical structure with range of 30 km (short-range scale) and a spherical structure with range of 140 km (long-range scale) in the linear model of coregionalization fitted. The spatial distribution features of seven heavy metals at short-range scale reflect "spot-like" or "stripe-like" local-scale spatial variations; the spatial distribution features of the seven heavy metals at long-range scale represent "slice-like" regional-scale spatial variations. At local scale, Zn, Cr, Ni, Cu, Pb and Cd are derived primarily from parent materials of Hainan Island, Leizhou Peninsula and Guangxi land, whose spatial distribution characteristics are controlled by granularity of sediments, while As is influenced dominantly by human pollution components from Hainan Island and Leizhou Peninsula. At regional scale, Zn, Cr, Ni and Cu originate primarily from parent rock materials of Leizhou Peninsula and Hainan Island, secondly from Guangxi land; As originated primarily from parent rock materials from Hainan Island, secondly from Leizhou Peninsula and Guangxi land. These metals are transported and migrated with sediments dominated by the anticlockwise circulation of Beibu Gulf year-round, deposited in "convergence center", forming the whole sedimentary pattern in direction of NWW-NNW at regional scale. The difference in distribution type between As and other metals at regional scale is mainly due to their different geochemical behavior.
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  • Alloway B J. 1995. Heavy Metals in Soils. London:Blackie Academic &Professional
    Castrignanò A, Giugliarini L, Risaliti R, et al. 2000. Study of spatial relationships among some soil physico-chemical properties of a field in central Italy using multivariate geostatistics. Geoderma, 97(1-2):39-60
    Chen Shengli, Hu Jianyu, Qi Yiquan. 2011. Circulation in Beibu Gulf.In:Su Jilan, ed. China Regional Oceanography (in Chinese).
    Beijing:China Ocean Press, 341-348
    CSBTS (China State Bureau of Quality and Technical Supervision). 2002. GB 18668-2002 Marine Sediment Quality. Beijing:Standards Press of China, 243-245
    Ding Shijiang, Huang Xiangding, Li Zhongjian, et al. 2001. Geological features and minerialzation of the Baolun gold deposit, Hainan.Chinese Geology (in Chinese), 28(5):18, 28-34
    Dou Yanguang, Li Jun, Li Yan. 2012. Rare earth element compositions and provenance implication of surface sediments in the eastern Beibu Gulf. Geochimica (in Chinese), 41(2):147-157
    Dou Yanguang, Li Jun, Zhao Jingtao, et al. 2013. Distribution, enrichment and source of heavy metals in surface sediments of the eastern Beibu Bay, South China Sea. Marine Pollution Bulletin, 67(1-2):137-145
    Emery X. 2010. Iterative algorithms for fitting a linear model of coregionalization.Computers & Geosciences, 36(9):1150-1160
    Flynn H C, Mc Mahon V, Diaz G C, et al. 2002. Assessment of bioavailable arsenic and copper in soils and sediments from the Antofagasta region of northern Chile. Science of The Total Environment, 286(1-3):51-59
    Gan Huayang, Lin Jinqin, Liang Kai, et al. 2013. Selected trace metals(As, Cd and Hg) distribution and contamination in the coastal wetland sediment of the northern Beibu Gulf, South China Sea.Marine Pollution Bulletin, 66(1-2):252-258
    Goovaerts P. 1992. Factorial kriging analysis:a useful tool for exploring the structure of multivariate spatial soil information. Journal of Soil Science, 43(4):597-619
    Goovaerts P. 1997. Geostatistics for Natural Resources Evaluation.New York:Oxford University Press
    Goovaerts P, Webster R. 1994. Scale-dependent correlation between topsoil copper and cobalt concentrations in Scotland.European Journal of Soil Science, 45(1):79-95
    Gu Yangguang, Wang Zhaohui, Lu Songhui, et al. 2012. Multivariate statistical and GIS-based approach to identify source of anthropogenic impacts on metallic elements in sediments from the mid Guangdong coasts, China. Environmental Pollution, 163:248-255
    Hu Bangqi, Cui Ruyong, Li Jun, et al. 2013. Occurrence and distribution of heavy metals in surface sediments of the Changhua River Estuary and adjacent shelf (Hainan Island). Marine Pollution Bulletin, 76(1-2):400-405
    Ip C C M, Li Xiangdong, Zhang Gan, et al. 2007. Trace metal distribution in sediments of the Pearl River Estuary and the surrounding coastal area, South China. Environmental Pollution, 147(2):311-323
    Irabien M J, Velasco F. 1999. Heavy metals in Oka river sediments(Urdaibai National Biosphere Reserve, northern Spain):Lithogenic and anthropogenic effects. Environmental Geology, 37(1):54-63
    Li Jun, Gao Jianhua, Wang Yaping, et al. 2012. Distribution and dispersal pattern of clay minerals in surface sediments, eastern Beibu Gulf, South China Sea. Acta Oceanologica Sinica, 31(2):78-87
    Liao Xiangui. 1986. Geochemical characteristics of arsenic in sediments from Bohai Gulf. Acta Oceanologoca Sinica, 5(2):215-219
    Liao Xiangjun, Wang Pingan, Ding Shijiang, et al. 2005. Main minerogenetic series and metallogenic characteristics on Hainan Island.Journal of Geomechanics (in Chinese), 11(2):187-194
    Lin C E, Chen C T, Kao C M, et al. 2011. Development of the sediment and water quality management strategies for the Salt-water River, Taiwan. Marine Pollution Bulletin, 63(5-12):528-534
    Loring D H, Rantala R T T. 1992. Manual for the geochemical analyses of marine sediments and suspended particulate matter.Earth-Science Reviews, 32(4):235-283
    Lv Jianshu, Liu Yang, Zhang Zulu, et al. 2013. Factorial kriging and stepwise regression approach to identify environmental factors influencing spatial multi-scale variability of heavy metals in soils. Journal of Hazardous Materials, 261:387-397
    Ma Ronglin, Yang Yi, He Yusheng. 2010. Geochemistry of rare earth elements in coastal and estuarial areas of Hainan's Nandu River. Journal of the Chinese Rare Earth Society (in Chinese), 28(1):110-114
    Ma Xinian, Li Quansheng, Shen Wanren, et al. 1984. The relationships between arsenic and other elements (Iron, Aluminium, Manganese etc) in surface sediments of Bohai Bay. Oceanologia et Limnologia Sinica (in Chinese), 15(5):448-456
    Neto J A B, Gingele F X, Leipe T, et al. 2006. Spatial distribution of heavy metals in surficial sediments from Guanabara Bay:Rio de Janeiro, Brazil. Environmental Geology, 49(7):1051-1063
    Nicholson F A, Smith S R, Alloway B J, et al. 2003. An inventory of heavy metals inputs to agricultural soils in England and Wales.Science of The Total Environment, 311(1-3):205-219
    Oliver M A. 1987. Geostatistics and its application to soil science. Soil Use and Management, 3(1):8-20
    Pan Ke, Wang Wenxiong. 2012. Trace metal contamination in estuarine and coastal environments in China. Science of the Total Environment, 421-422:3-16
    Paul C J, Ford R G, Wilkin R T. 2009. Assessing the selectivity of extractant solutions for recovering labile arsenic associated with iron (hydr) oxides and sulfides in sediments. Geoderma, 152(1-2):137-144
    Smedley P L, Kinniburgh D G. 2002. A review of the source, behaviour and distribution of arsenic in natural waters. Applied Geochemistry, 17(5):517-568
    Sollitto D, Romic M, Castrignanò A, et al. 2010, Assessing heavy metal contamination in soils of the Zagreb region (Northwest Croatia)using multivariate geostatistics. Catena, 80(3):182-194
    Sun Xiangping. 2005. In:Su Jilan, ed. Hydrological Characteristics and Circulation of Beibu Gulf, in Offshore Hydrology of China Sea (in Chinese). Beijing:China Ocean Press, 285-296
    Tong Guobang, Chen Liang, Long Jiangping, et al. 2012. Surface pollen distribution patterns in Beibu Gulf and corresponding sediment dynamics environment. Chinese Science Bulletin, 57(8):902-911
    Varol M, Sen B. 2012. Assessment of nutrient and heavy metal contamination in surface water and sediments of the upper Tigris River, Turkey. Catena, 92:1-10
    Wackernagel H. 1994. Cokriging versus kriging in regionalized multivariate data analysis. Geoderma, 62(1-3):83-92
    Wang Shuailong, Xu Xiangrong, Sun Yuxin, et al. 2013. Heavy metal pollution in coastal areas of South China:A review. Marine Pollution Bulletin, 76(1-2):7-15
    Webster R. 1985. Quantitative Spatial analysis of soil in the field. In:Stewart B A, ed. Advances in Soil Science. New York:Springer, 3:1-70
    Xia Peng, Meng Xianwei, Yin Ping, et al. 2011. Eighty-year sedimentary record of heavy metal inputs in the intertidal sediments from the Nanliu River estuary, Beibu Gulf of South China Sea.Environmental Pollution, 159(1):92-99
    Xiao Xiyuan, Chen Tongbin, Liao Xiaoyong, et al. 2008. Regional distribution of arsenic contained minerals and arsenic pollution in China. Geographical Research (in Chinese), 27(1):201-212
    Xu Dong. 2014. Sedimentary records since last deglaciation and the formation of modern sedimentary pattern in eastern Beibu Gulf[dissertation] (in Chinese). Qingdao:Institute of Oceanology, Chinese Academy of Sciences
    Xu Zhiwei, Wang Yaping, Li Yan, et al. 2010. Sediment transport patterns in the eastern Beibu Gulf based on grain-size multivariate statistics and provenance analysis. Haiyang Xue bao (in Chinese), 32(3):67-78
    Yu Ruilian, Yuan Xing, Zhao Yuanhui, et al. 2008. Heavy metal pollution in intertidal sediments from Quanzhou Bay, China. Journal of Environmental Sciences, 20(6):664-669
    Zhang Zhiping, Lan Jinyi. 2012. Research on excessive municipal sewage of coastal cities of Guangxi in 2011. Science & Association Forum (in Chinese), (6):129-130
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